1 - Equip the tools and settings needed to get started in web design
To start writing the design code you need a program to write the code called code editor and this list of programs that benefit you to choose from them.
Like: Brackets , KomodoEdit , ++Notepad , Atom
A modern browser to see your design like [Google Chrome] or [Firefox Developer Edition]
2 - Start learning HTML to create your first page on the web.
HTML
3 - He started learning CSS to format web pages.
CSS
3 - After learning languages and watching tips comes practical application time.
free CSS template in Google and practice more practice more practice..........
4 - Start learning the new version of Html (HTML5)
HTML5 , HTML5.1 : more features
5 - Start learning the new version of CSS
CSS3: more features
6 - What do you learn after building a web page and designing it? You have to do the magic touches.
Javascript, framework jquery ++ framework
7 - The second application time came after we learned the jQuery library
free CSS template jquery
8 - More Practice
the secret: More Practice
9 - Responsive design
Css3 Or Framework Bootstrap
10 - Advanced tools for professionalism
SASS

References:w3schools
youtube Just tip language you want to learn
developer.mozilla.org

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Yes because WordPress is CMS don't need much knowledge to modify in template bat HTML CSS Is the first step to become designer or programmer ( i will write web programmer paths (Full) ) After HTML CSS jquery in frontend devloper , backend ( c# php , perl , javascript+framwork++++)